Pioneer Settlers of Grayson County, Virginia - Paperbackby Benjamin F. Nuckolls (Author) Grayson County, Virginia, was formed in 1792 from portions of Patrick and Wythe Counties, and is located near the convergence of the North Carolina and Tennessee borders. The county is bounded by New River and Wythe County on the North, and by the Blue Ridge and state of North Carolina on the South, and was first known as Botetourt District, and afterwards, as Washington and Montgomery Districts. This work provides a